Which of the following species is not electrophilic in nature?

$A$ lens having focal length $f$ and aperture of diameter $d$ forms an image of intensity $I$. If the central region of the lens with diameter $\frac{d}{2}$ is covered by black paper,what will be the new focal length and intensity of the image?

Choose the incorrect statement from the following:
$S1:$ The efficiency of a heat engine can be $1$,but the coefficient of performance of a refrigerator can never be infinity.
$S2:$ The first law of thermodynamics is basically the principle of conservation of energy.
$S3:$ The second law of thermodynamics does not allow several phenomena consistent with the first law.
$S4:$ $A$ process,whose only result is to transfer heat from a colder to a hotter object,is impossible.

$A$ clock which keeps correct time at $20^{\circ} C$,is subjected to $40^{\circ} C$. If the coefficient of linear expansion of the pendulum is $12 \times 10^{-6} /{ }^{\circ} C$,how much time will it gain or lose per day?

If the rate of disappearance of $N_2O_5$ in the following reaction is $1.2 \times 10^{-5} \ mol \ L^{-1} \ s^{-1}$,the rate of production of $NO_2$ in $mol \ L^{-1} \ s^{-1}$ is:
$2 \ N_2O_{5(g)} \longrightarrow 4 \ NO_{2(g)} + O_{2(g)}$

The radius of the first orbit of hydrogen is $r_{H}$,and the energy in the ground state is $-13.6 \text{ eV}$. Considering a $\mu^{-}$-particle with a mass $207 m_e$ revolving around a proton as in a hydrogen atom,the energy and radius of the proton and $\mu^{-}$-combination respectively in the first orbit are (assume the nucleus to be stationary):